Dr. Markus Klapper

Markus Klapper studied chemistry at the University of Mainz and received his doctorate in 1990 from Prof. R. C. Schulz with a thesis on the synthesis and topochemical polymerization of aminodiacetylenes. Soon after, he moved to the MPI for Polymer Research and became project leader in the Department of Synthetic Chemistry. His research interests include new polycondensation and polymerization processes as well as polymer-analogous reactions for the synthesis of functional polymers and block copolymers. These materials have been specially developed for fuel cell applications or for hydrophobizing inorganic nanoparticles. In addition, in recent years he has concentrated on the polymerization of olefins in heterogeneous phase, for which he has developed new organic carriers and investigated their polymerization behavior. Another central topic is the development of non-aqueous emulsions suitable for the polymerization of water-sensitive monomers.

Research Interest

Modern polymer science must develop materials that are sustainable across their full life cycle while enabling energy-efficient industrial processes. We address these challenges through innovative synthetic strategies inspired by biological principles.

Central to the group’s vision is the concept that true sustainability requires new chemical principles, not incremental modification of existing plastics. In one approach of the pioneering research a light-triggered degradability is encoded directly into polymers using molecular photosensitizers. In a different project, in cooperation with Tanja Weil, we engineer ultrathin functional membranes inspired by biological compartmentalization, enabling ion sieving, molecular filtration, and bio-sensing with minimal energy input.

Selected Publications

Journal Article (63)

1.
Journal Article
Megahed, S.; Wutke, N.; Liu, Y.; Klapper, M.; Schulz, F.; Feliu, N.; Parak, W. J.: Encapsulation of Nanoparticles with Statistical Copolymers with Different Surface Charges and Analysis of Their Interactions with Proteins and Cells. International Journal of Molecular Sciences 25, 5539, p. 10 (2024)
2.
Journal Article
Schulz, F.; Hühn, J.; Werner, M.; Hühn, D.; Kvelstad, J.; Koert, U.; Wutke, N.; Klapper, M.; Fröba, M.; Baulin, V. et al.; Parak, W. J.: Local Environments Created by the Ligand Coating of Nanoparticles and Their Implications for Sensing and Surface Reactions. Accounts of Chemical Research 56 (17), pp. 2278 - 2285 (2023)
3.
Journal Article
Valdeperez, D.; Wutke, N.; Ackermann, L.-M.; Parak, W. J.; Klapper, M.; Pelaz, B.: Colloidal stability of polymer coated zwitterionic Au nanoparticles in biological media. Inorganica Chimica Acta 534, 120820 (2022)
4.
Journal Article
Hejazi-Dehaghani, Z.-A.; Arabi, H.; Thalheim, D.; Vidakovic, D.; Haghighi, M. N.; Veith, L.; Klapper, M.: Organic Versus Inorganic Supports for Metallocenes: The Influence of Rigidity on the Homogeneity of the Polyolefin Microstructure and Properties. Macromolecules 54 (6), pp. 2667 - 2680 (2021)
5.
Journal Article
Kluthe, K.; Wagner, M.; Klapper, M.: Simultaneous Bottlebrush Polymerization. Macromolecules 54 (3), pp. 1465 - 1477 (2021)
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